Stabilization of High-Performance Oxygen Reduction Reaction Pt Electrocatalyst Supported on Reduced Graphene Oxide/Carbon Black Composite

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• 作者：Yujing Li ; Yongjia Li ; Enbo Zhu ; Tait McLouth ; Chin-Yi Chiu ; Xiaoqing Huang ; Yu Huang
• 刊名：The Journal of the American Chemical Society
• 出版年：2012
• 出版时间：August 1, 2012
• 年：2012
• 卷：134
• 期：30
• 页码：12326-12329
• 全文大小：322K
• 年卷期：v.134,no.30(August 1, 2012)
• ISSN：1520-5126

文摘

Oxygen reduction reaction (ORR) catalyst supported by hybrid composite materials is prepared by well-mixing carbon black (CB) with Pt-loaded reduced graphene oxide (RGO). With the insertion of CB particles between RGO sheets, stacking of RGO can be effectively prevented, promoting diffusion of oxygen molecules through the RGO sheets and enhancing the ORR electrocatalytic activity. The accelerated durability test (ADT) demonstrates that the hybrid supporting material can dramatically enhance the durability of the catalyst and retain the electrochemical surface area (ECSA) of Pt: the final ECSA of the Pt nanocrystal on the hybrid support after 20鈥?00 ADT cycles is retained at >95%, much higher than the commercially available catalyst. We suggest that the unique 2D profile of the RGO functions as a barrier, preventing leaching of Pt into the electrolyte, and the CB in the vicinity acts as active sites to recapture/renucleate the dissolved Pt species. We furthermore demonstrate that the working mechanism can be applied to the commercial Pt/C product to greatly enhance its durability.