Combining Cyanometalates and Coordination Clusters: An Alternative Synthetic Route toward Original Molecular Materials

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• 作者：Abhishake Mondal ; Pierre-Igor Dassi茅 ; Lise-Marie Chamoreau ; Yves Journaux ; Miguel Julve ; Laurent Lisnard ; Rodrigue Lescou毛zec
• 刊名：Crystal Growth & Design
• 出版年：2013
• 出版时间：October 2, 2013
• 年：2013
• 卷：13
• 期：10
• 页码：4190-4194
• 全文大小：261K
• 年卷期：v.13,no.10(October 2, 2013)
• ISSN：1528-7505

文摘

As an original synthetic route to molecular magnetic materials, we have reacted partially-blocked cyanometalates with preformed coordination cluster. The association of the fac-[Fe(Tp)(CN)₃]^{鈭?/sup> assembling metalloligand with the [Cu₃(OH)(pz)₃]2+ trigonal cluster has afforded a novel coordination network where the trimetallic copper(II) nodes are linked by the iron(III) complexes into chains and by coordinating acetate into a two-dimensional framework.}