Supramolecular Structures Based on Bis(2-hydroxy-5-chlorophenyl) Sulfide and Spirobicromane with Bipyridines

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• 作者：Qingdao Zeng ; Dongxia Wu ; Chen Wang ; Hongwei Ma ; Jun Lu ; Caiming Liu ; Shandong Xu ; Yan Li ; and Chunli Bai
• 刊名：Crystal Growth & Design
• 出版年：2005
• 出版时间：September 2005
• 年：2005
• 卷：5
• 期：5
• 页码：1889 - 1896
• 全文大小：688K
• 年卷期：v.5,no.5(September 2005)
• ISSN：1528-7505

文摘

Six new supramolecular structures have been prepared by bis(2-hydroxy-5-chlorophenyl) sulfide (HCS)and/or spirobicromane (SBC) with bipyridine bases 4,4'-bipyridyl (bipy), 1,2-di(4-pyridyl)ethylene (dipy-ete), 1,2-bis(4-pyridyl)ethane (bipy-eta), and 4,4'-dipyridyl N,N'-dioxide (dipy-dox). These molecular complexes are (HCS)·(bipy) 1, (HCS)·(dipy-ete) 2, (HCS)·(bipy-eta) 3, (HCS)·(dipy-dox) 4, (SBC)·(dipy-ete) 5, and (SBC)·(dipy-dox)·H₂O 6,respectively. The crystal structures of 1-6 have been determined by single crystal X-ray diffraction. All of thesemolecular complexes exhibit supramolecular structures via O-H···N or O-H···O hydrogen bondings. Both 1 and 2form interestingly [2 + 2] macrocyclic structures, whose sizes are ca. 12.495(6) Å × 5.087(6) Å and 14.774(6) Å ×5.300(6) Å, respectively. Compounds 3 and 5 form one-dimensional zigzag chain structures. Compounds 4 and 6form two-dimensional double helices. These results demonstrate that by changing the guest molecule, we can obtaindifferent hydrogen-bonded supramolecular structures through different interactions.