Resonant Inelastic X-ray Scattering of Molybdenum Oxides and Sulfides
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- 作者：Rowena Thomas ; Josh Kas ; Pieter Glatzel ; Mustafa Al Samarai ; Frank M. F. de Groot ; Roberto Alonso Mori ; Matja啪 Kav膷i膷 ; Matjaz Zitnik ; Klemen Bucar ; John J. Rehr ; Moniek Tromp
- 刊名：Journal of Physical Chemistry C
- 出版年：2015
- 出版时间：February 5, 2015
- 年：2015
- 卷：119
- 期：5
- 页码：2419-2426
- 全文大小：509K
- ISSN：1932-7455
文摘
Molybdenum oxides and sulfides were studied using resonant inelastic X-ray scattering (RIXS). The 2p3/23d Mo RIXS planes show a rich structure with considerably more spectral information than in conventional X-ray absorption near edge structure (XANES) spectroscopy. The spectra were simulated using FEFF9 giving generally good agreement and detailed electronic information can be derived. The reference materials serve as a starting point for detailed electronic and geometric investigations of a broad range of compounds. In particular, this can provide insights in the properties and performance of unknown and changing materials like those in catalysis.