In(OH)BDC·0.75BDCH2 (BDC = Benzenedicarboxylate), a Hybrid Inorganic-Organic Vernier Structure

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• 作者：Ekaterina V. Anokhina ; Marie Vougo-Zanda ; Xiqu Wang ; and Allan J. Jacobson
• 刊名：Journal of the American Chemical Society
• 出版年：2005
• 出版时间：November 2, 2005
• 年：2005
• 卷：127
• 期：43
• 页码：15000 - 15001
• 全文大小：103K
• 年卷期：v.127,no.43(November 2, 2005)
• ISSN：1520-5126

文摘

The compound In(OH)BDC·0.75BDCH₂ (BDC = benzenedicarboxylate), 1, has been synthesized and characterized by single-crystal X-ray diffraction. The structure comprises two distinct sublattices formed by a covalently linked In(OH)BDC lattice and ordered chains of hydrogen-bonded H₂BDC molecules and can be described as a hybrid inorganic coordination polymer-organic vernier structure. Each InO₆ octahedron of the octahedral chain has a length of 3.6 Å along the chain axis, whereas each H₂BDC molecule has a length of 9.6 Å along the guest column axis. Therefore, a unit of eight InO₆ octahedra of the octahedral chain is just in registry with three H₂BDC molecules of the guest column giving a repeat unit of 28.76 Å along the channel axis direction.