Unusual self-assembled nanoaggregation of the thermally stable metal-free slipped-cofacial J-type phthalocyanine dimer

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• 关键词：Nanoaggregation ; Phthalocyanine ; J-type dimer ; Electron microscopy
• 刊名：Chinese Chemical Letters
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：28
• 期：1
• 页码：89-91
• 全文大小：869 K
• 卷排序：28

文摘

Nanoaggregation of the thermally stable bis(2-hydroxy-9(10),16(17),23(24)-tri-tert-butylphthalocyanine) of J-type was observed by the field emission scanning electron microscopy (FE-SEM). Ordered phases, represented as threads composed of about 200 nm diameter circles were discovered, unlike the parent dimeric magnesium complex, in which similar circles combine together to give visually distinguishable zones with widths of about 600 nm and the same distance between them.