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Si-B-C-N monoliths with LaB6-induced well-developed BN(C) flakes
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LaB6 was incorporated into Si-B-C-N monoliths by mechanical alloying technique.

Thin BN(C) flakes are in situ formed in Si-B-C-N ceramics due to the LaB6 additive.

BN(C) flakes play a dominate role in improving the ceramic's toughness.

Solid-solution of La in BN(C) grains promotes in situ growth of BN(C) flakes.

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