Synthesis of axially chiral oxazoline-carbene coordinated palladium complexes with a N-phenyl framework

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• 作者：Dong-Dong Zhang^a ; ¹ ; Yun-Long Liu^a ; ¹ ; Yan Wang^a ; Hao Wei^b ; ^{haowei@sjtu.edu.cn" class="auth_mail" title="E-mail the corresponding author} ; Min Shi^a ; ^c ; Fei-Jun Wang^a ; ^{feijunwang@ecust.edu.cn" class="auth_mail" title="E-mail the corresponding author}
• 关键词：tropos ligand ; Copper catalyzed cross-coupling of N-C bond ; Axially chiral ; Palladium complex ; N-Phenyl framework
• 刊名：Chinese Chemical Letters
• 出版年：2016
• 出版时间：April 2016
• 年：2016
• 卷：27
• 期：4
• 页码：563-565
• 全文大小：932 K

文摘

A family of tropos ligands bearing a N-heterocyclic carbene and a chiral oxazoline coordination group with a N-phenyl framework were easily prepared, and their coordination behavior with Pd(II) acetate was performed, affording a series of axially chiral palladium complexes in good yields.