Synthesis, spectral elucidation, electrochemistry and DFT interpretation of manganese(II)-thioalkyl-arylazoimidazole complex

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• 作者：Soumendranath Nandi^a ; Kuheli Das^a ; ¹ ; Amitabha Datta^a ; ¹ ; ^{amitd_ju@yahoo.co.in} ; Debashis Banerjee^a ; Suman Roy^a ; Tapan Kumar Mondal^a ; Debashree Mandal^b ; Prasanta Kumar Nanda^b ; Takashiro Akitsu^c ; Shinnosuke Tanaka^c ; Chittaranjan Sinha^a ; ^{c_r_sinha@yahoo.com}
• 关键词：1-Alkyl-2-{(thioalkyl)arylazo}imidazole ; Manganese(II) ; Crystal structure ; Spectra ; Electrochemistry
• 刊名：Journal of Molecular Structure
• 出版年：2017
• 出版时间：5 April 2017
• 年：2017
• 卷：1133
• 期：Complete
• 页码：574-579
• 全文大小：1311 K
• 卷排序：1133

文摘

Thioalkylphenylazoimidazole Mn(II) complex. Structural confirmation by single crystal X-ray diffraction. Variable temperature magnetism and antiferromagnetic property. Cyclic voltammetry shows Mn(III)/Mn(II) redox response. EPR spectra and super-hyperfine splitting.