Synthesis, UV/vis, FT-IR and Mössbauer spectroscopic characterization and molecular structure of the Bis[4-(2-aminoethyl)morpholine](tetrakis(4-metoxyphenyl)porphyrinato) iron(II) complex
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- 作者：Leila Ben Haj Hassena ; Khaireddine Ezzayania ; zayanikh2015@gmail.com" class="auth_mail" title="E-mail the corresponding author ; Yoann Rousselinb ; Christine Sternb ; Habib Nasria ; Charles E. Schulzc
- 关键词：Iron porphyrin complex ; X-ray diffraction ; UV-visible ; Mö ; ssbauer
- 刊名：Journal of Molecular Structure
- 出版年：2016
- 出版时间：15 April 2016
- 年：2016
- 卷：1110
- 期：Complete
- 页码：138-142
- 全文大小：764 K
文摘
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UV–visible spectrum shows redshifted Soret and Q bands.
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Soret and Q bands at 424, 534 and 574 nm are close to those of reported iron(II)-bis(amine) porphyrins.
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Mössbauer parameters indicates a Low-spin (LS) (S = 0) iron(II)-porphyrin complexes.
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The average equatorial iron–N(pyrrole) distance is characteristic of LS ferrous porphyrins.
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