Cover Picture: Selective Hydrogen Generation from Formic Acid with Well-Defined Complexes of Ruthenium and Phosphorus-Nitrogen PN3-Pincer Ligand (Chem. Asian J. 9/2016)

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• 作者：Dr. Yupeng Pan ; Dr. Cheng-Ling Pan ; Yufan Zhang ; Dr. Huaifeng Li ; Dr. Shixiong Min ; Dr. Xunmun Guo ; Dr. Bin Zheng ; Dr. Hailong Chen ; Addison Anders ; Prof. Zhiping Lai ; Prof. Junrong Zheng and Prof. Kuo-Wei Huang
• 刊名：Chemistry – An Asian Journal
• 出版年：2016
• 出版时间：May 6, 2016
• 年：2016
• 卷：11
• 期：9
• 页码：1294
• 全文大小：221K
• ISSN：1861-471X

文摘

Formic acid (HCOOH) has been considered as a potential liquid source and storage material for hydrogen. Its high volumetric hydrogen capacity of 53 g H₂ L⁻, equivalent to an energy density of 1.77 kW h L⁻¹, makes it attractive for automotive and mobile applications. A new class of PN³-pincer complexes were employed for the selective hydrogen generation from HCOOH, and a long life time of 150 h with a turnover number over 1 million was achieved. More information can be found in the Communication by Kuo-Wei Huang and Junrong Zheng et al. on page 1357 in Issue 9, 2016 (DOI: 10.1002/asia.201600169).