Hydroacenes Made Easy by Gold(I) Catalysis

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• 作者：Ruth Dorel ; Dr. Paul R. McGonigal and Prof. Dr. Antonio M. Echavarren
• 刊名：Angewandte Chemie International Edition
• 出版年：2016
• 出版时间：September 5, 2016
• 年：2016
• 卷：55
• 期：37
• 页码：11120-11123
• 全文大小：1790K
• ISSN：1521-3773

文摘

A novel strategy for the synthesis of partially saturated acene derivatives has been developed based on a Au^I-catalyzed cyclization of 1,7-enynes. This method provides straightforward access to stable polycyclic products featuring the backbone of the acene series, up to nonacene.