In this paper, lithology (mostly sand and gravel) and the vadose zone of the Luohe bed near Luoyang are examined. The Luohe bed is composed of sub-clay, sub-sand, medium fine sand and other media. The self-purification ability of pollutants of the river bed and the vadose zone is analyzed. The natural self-purification mechanism is briefly analyzed. The results show that the self-purification ability of pollutants of the Luohe bed is as high as 90% (except NO-3). Sub-clay, sub-sand, medium fine sand and other dielectric layer of vadose zone have a strong capacity to purify heavy metal (Cu2+), but is weak to clean Cl-and Cr6+, because the media can reach saturation state and lose the capacity purification in a short time.